| Winner | Loser | Tournament | Date | Prob | Odds1 | Odds2 | Sets | $Bet1 | $Bet2 | Profit |
| Anna-Lena Groenefeld | Jill Craybas | Fed Cup, World Group I 2006, 1R, GER-USA | 23.04.2006 | 81% | $ 1,01 | $ 1,01 | 2-0 | $ - | $ - | $ - |
| Anabel Medina Garrigues | Sybille Bammer | Fed Cup, World Group I 2006, 1R, ESP-AUT | 23.04.2006 | 66% | $ 1,01 | $ 1,01 | 2-0 | $ - | $ - | $ - |
| Francesca Schiavone | Amelie Mauresmo | Fed Cup, World Group I 2006, 1R, FRA-ITA | 23.04.2006 | 28% | $ 1,01 | $ 1,01 | 2-1 | $ - | $ - | $ - |
| Elena Dementieva | Kim Clijsters | Fed Cup, World Group I 2006, 1R, BEL-RUS | 22.04.2006 | 42% | $ 1,01 | $ 1,01 | 2-0 | $ - | $ - | $ - |
| Justine Henin-Hardenne | Nadia Petrova | Fed Cup, World Group I 2006, 1R, BEL-RUS | 22.04.2006 | 40% | $ 1,01 | $ 1,01 | 2-1 | $ - | $ - | $ - |
| Jamea Jackson | Anna-Lena Groenefeld | Fed Cup, World Group I 2006, 1R, GER-USA | 22.04.2006 | 18% | $ 1,01 | $ 1,01 | 2-1 | $ - | $ - | $ - |
| Jill Craybas | Julia Schruff | Fed Cup, World Group I 2006, 1R, GER-USA | 22.04.2006 | 57% | $ 1,01 | $ 1,01 | 2-1 | $ - | $ - | $ - |
| Lourdes Dominguez-Lino | Sybille Bammer | Fed Cup, World Group I 2006, 1R, ESP-AUT | 22.04.2006 | 63% | $ 1,01 | $ 1,01 | 2-1 | $ - | $ - | $ - |
| Anabel Medina Garrigues | Yvonne Meusburger | Fed Cup, World Group I 2006, 1R, ESP-AUT | 22.04.2006 | 71% | $ 1,01 | $ 1,01 | 2-0 | $ - | $ - | $ - |
| Francesca Schiavone | Nathalie Dechy | Fed Cup, World Group I 2006, 1R, FRA-ITA | 22.04.2006 | 76% | $ 1,01 | $ 1,01 | 2-1 | $ - | $ - | $ - |
| Amelie Mauresmo | Flavia Pennetta | Fed Cup, World Group I 2006, 1R, FRA-ITA | 22.04.2006 | 85% | $ 1,01 | $ 1,01 | 2-0 | $ - | $ - | $ - |
| $ - | $ - | $ - |